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A line of atoms of the same type in a molecule. In a straight chain the atoms are attached only to single atoms, not to groups. Propane, for instance, is a straight-chain alkane, CH3CH2CH3, with a chain of three carbon atoms. A branched chain is one in which there are side groups attached to the chain. Thus, 3-ethyloctane, CH3CH2CH(C2H5)C5H11, is a branched-chain alkane in which there is a side chain (C2H5) attached to the third carbon atom. A closed chain is a ring of atoms in a molecule; otherwise the molecule has an open chain.

Subjects: Chemistry.

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