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A colourless gas, (CN)2, with a pungent odour; soluble in water, ethanol, and ether; d. 2.335 g dm−3; m.p. –27.9°C; b.p. –20.7°C. The compound is very toxic. It may be prepared in the laboratory by heating mercury(II) cyanide; industrially it is made by gas-phase oxidation of hydrogen cyanide using air over a silver catalyst, chlorine over activated silicon(IV) oxide, or nitrogen dioxide over a copper(II) salt. Cyanogen is an important intermediate in the preparation of various fertilizers and is also used as a stabilizer in making nitrocellulose. It is an example of a pseudohalogen.

Subjects: Chemistry.

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