nitric acid

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A colourless corrosive poisonous liquid, HNO3; r.d. 1.50; m.p. –42°C; b.p. 83°C. Nitric acid may be prepared in the laboratory by the distillation of a mixture of an alkali-metal nitrate and concentrated sulphuric acid. The industrial production is by the oxidation of ammonia to nitrogen monoxide, the oxidation of this to nitrogen dioxide, and the reaction of nitrogen dioxide with water to form nitric acid and nitrogen monoxide (which is recycled). The first reaction (NH3 to NO) is catalysed by platinum or platinum/rhodium in the form of fine wire gauze. The oxidation of NO and the absorption of NO2 to form the product are noncatalytic and proceed with high yields but both reactions are second-order and slow. Increases in pressure reduce the selectivity of the reaction and therefore rather large gas absorption towers are required. In practice the absorbing acid is refrigerated to around 2°C and a commercial ‘concentrated nitric acid’ at about 67% is produced.

Nitric acid is a strong acid (highly dissociated in aqueous solution) and dilute solutions behave much like other mineral acids. Concentrated nitric acid is a strong oxidizing agent. Most metals dissolve to form nitrates but with the evolution of nitrogen oxides. Concentrated nitric acid also reacts with several nonmetals to give the oxo acid or oxide. Nitric acid is generally stored in dark brown bottles because of the photolytic decomposition to dinitrogen tetroxide. See also nitration.

Subjects: Chemistry.

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