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sodium peroxide


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A whitish solid (yellow when hot), Na2O2, soluble in ice-water and decomposed in warm water or alcohol; r.d. 2.80; decomposes at 460°C. A crystalline octahydrate (hexagonal) is obtained by crystallization from ice-water. The compound is formed by the combustion of sodium metal in excess oxygen. At normal temperatures it reacts with water to give sodium hydroxide and hydrogen peroxide. It is a powerful oxidizing agent reacting with iodine vapour to give the iodate and periodate, with carbon at 300°C to give the carbonate, and with nitrogen(II) oxide to give the nitrate. It is used as a bleaching agent in wool and yarn processing, in the refining of oils and fats, and in the production of wood pulp.

Subjects: Chemistry.


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