tin(II) sulphide

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A grey-black cubic or monoclinic solid, SnS, virtually insoluble in water; r.d. 5.22; m.p. 882°C; b.p. 1230°C. It has a layer structure similar to that of black phosphorus. Its heat of formation is low and it can be made by heating the elements together. Above 265°C it slowly decomposes (disproportionates) to tin(IV) sulphide and tin metal. The compound reacts with hydrochloric acid to give tin(II) chloride and hydrogen sulphide.

Subjects: Chemistry.

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