Weston cell

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A type of primary voltaic cell devised by Edward Weston (1850–1936), which is used as a standard; it produces a constant e.m.f. of 1.0186 volts at 20°C. The cell is usually made in an H-shaped glass vessel with a mercury anode covered with a paste of cadmium sulphate and mercury(I) sulphate in one leg and a cadmium amalgam cathode covered with cadmium sulphate in the other leg. The electrolyte, which connects the two electrodes by means of the bar of the H, is a saturated solution of cadmium sulphate. In some cells sulphuric acid is added to prevent the hydrolysis of mercury sulphate.

Subjects: Chemistry — Physics.

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