Rate coefficients for the radiative association of titanium and oxygen atoms to form the titanium monoxide (TiO) molecule are estimated. The radiative association of Ti(³F) and O(³P) atoms is dominated by an approach along the C³Δ potential energy curve, accompanied by spontaneous emission into the X³Δ ground state of TiO. For temperatures ranging from 300–14 000 K, the total rate coefficients are found to vary from 4.76 × 10⁻¹⁷ to 9.96 × 10⁻¹⁷ cm³ s⁻¹, respectively.

Rate coefficients for the radiative association of titanium and oxygen atoms to form the titanium monoxide (TiO) molecule are estimated. The radiative association of Ti(³F) and O(³P) atoms is dominated by an approach along the C³Δ potential energy curve, accompanied by spontaneous emission into the X³Δ ground state of TiO. For temperatures ranging from 300–14 000 K, the total rate coefficients are found to vary from 4.76 × 10⁻¹⁷ to 9.96 × 10⁻¹⁷ cm³ s⁻¹, respectively.